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71.
The weathering of mantle peridotite tectonically exposed to the atmosphere leads commonly to natural carbonation processes. Extensive cryptocrystalline magnesite veins and stock-work are widespread in the serpentinite sole of the New Caledonia ophiolite. Silica is systematically associated with magnesite. It is commonly admitted that Mg and Si are released during the laterization of overlying peridotites. Thus, the occurrence of these veins is generally attributed to a per descensum mechanism that involves the infiltration of meteoric waters enriched in dissolved atmospheric CO2. In this study, we investigate serpentinite carbonation processes, and related silicification, based on a detailed petrographic and crystal chemical study of serpentinites. The relationships between serpentine and alteration products are described using an original method for the analysis of micro-X-ray fluorescence images performed at the centimeter scale. Our investigations highlight a carbonation mechanism, together with precipitation of amorphous silica and sepiolite, based on a dissolution–precipitation process. In contrast with the per descensum Mg/Si-enrichment model that is mainly concentrated in rock fractures, dissolution–precipitation process is much more pervasive. Thus, although the texture of rocks remains relatively preserved, this process extends more widely into the rock and may represent a major part of total carbonation of the ophiolite.  相似文献   
72.
In situ monitoring of karst springs in Wallonia (southern Belgium)   总被引:1,自引:1,他引:0  
The implementation of the Water Framework Directive, as well as the forthcoming entry into force of other European water policies focusing on water resources, require a thorough reorganization of groundwater resources monitoring in most European countries. In Wallonia, monitoring programs were initiated in 2005 to control the quantitative and chemical statuses of groundwater bodies, as well as the effectiveness of management plans aimed at achieving environmental objectives. In karst aquifers, springs are preferential monitoring targets even if, as a result of the high heterogeneity of this type of aquifer, the interpretation of time series and spatial data remains a challenge. Since 2006, a “springs” monitoring network has been progressively set up in the southern part of Belgium. Currently, in situ measurements of discharge, temperature, conductivity, turbidity and fluorescence of water are conducted at nine karstic outlets in the Devonian and the Carboniferous limestone aquifers of Wallonia. The main objective of this ongoing research is to evaluate the suitability and the robustness of such standard measurements to discriminate anthropogenic impacts from natural variations, at both short- and long-term scales. Discharge and temperature data revealed being useful in the assessment of regional hydro-climatic trends. Groundwater proved to be a better natural filter for the assessment of long-term climatic changes than mathematical filtering of noisy surface signals. Investigations of such data at a European scale could therefore give additional insight into the impacts of climate change on groundwater resources. Conductivity, turbidity and fluorescence data characterize the particulate, mineral and organic health of water and a better understanding of their natural dynamics could help in the early detection of anthropogenic deviations. However, the current reproducibility of these measurements is too low to ascertain observed trends and fluctuations, and further research is still needed.  相似文献   
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This study investigates the effect of fine-scale clay drapes on tracer transport. A tracer test was performed in a sandbar deposit consisting of cross-bedded sandy units intercalated with many fine-scale clay drapes. The heterogeneous spatial distribution of the clay drapes causes a spatially variable hydraulic conductivity and sorption coefficient. A fluorescent tracer (sodium naphthionate) was injected in two injection wells and ground water was sampled and analyzed from five pumping wells. To determine (1) whether the fine-scale clay drapes have a significant effect on the measured concentrations and (2) whether application of multiple-point geostatistics can improve interpretation of tracer tests in media with complex geological heterogeneity, this tracer test is analyzed with a local three-dimensional ground-water flow and transport model in which fine-scale sedimentary heterogeneity is modeled using multiple-point geostatistics. To reduce memory needs and calculation time for the multiple-point geostatistical simulation step, this study uses the technique of direct multiple-point geostatistical simulation of edge properties. Instead of simulating pixel values, model cell edge properties indicating the presence of irregularly shaped surfaces are simulated using multiple-point geostatistical simulations. Results of a sensitivity analysis show under which conditions clay drapes have a significant effect on the concentration distribution. Calibration of the model against measured concentrations from the tracer tests reduces the uncertainty on the clay-drape parameters. The calibrated model shows which features of the breakthrough curves can be attributed to the geological heterogeneity of the aquifer and which features are caused by other processes.  相似文献   
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The influence of a hedge surrounding bottomland on soil‐water movement along the hillslope was studied on a plot scale for 28 months. The study was based on the comparison of two transects, one with a hedge, the other without, using mainly a dense grid of tensiometers. The influence of the bottomland hedge was located in the area where tree roots were developed, several metres upslope from the hedge, and could be observed both in the saturated and non‐saturated zone, from May to December. The hedge induced a high rate of soil drying, because of the high evaporative capacity of the trees. We evaluated that water uptake by the hedge during the growing season was at least 100 mm higher than without a hedge. This increased drying rate led to a delayed rewetting of the soils upslope from the hedge in autumn, of about 1 month compared with the situation without a hedge. Several consequences of this delayed rewetting are expected: a delay in the return of subsurface transfer from the hillslope to the riparian zone, a buffering effect of hedges on floods, already observed at the catchment scale, and an increased residence time of pollutants. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
77.
Armoured jawless fish, or 'ostracoderms', lived 450–360 million years ago, and display unusual morphologies, unlike any modern fish group. Since they left no living descendants, their mode of swimming has, until recently, remained speculative, although this is a crucial question as the first true pectoral fins evolved within the 'ostracoderms'. The discovery of the oldest-known fish trails, from the Early Devonian (400 million year old) 'Lower Old Red Sandstone' of south-east Wales offers new insights into the swimming behaviour of these early fish, notably the osteostracan 'ostracoderms' (or cephalaspids), whose horseshoe-shaped head and paddle-shaped pectoral fins have remained a functional riddle.  相似文献   
78.
Detailed studies of nearby cluster-forming molecular clouds can help us understand the physical processes by which most stars form in galaxies. I review recent advances made on this subject. Submillimeter observations of nearby protoclusters suggest that stars are generally built from finite, detached reservoirs of mass inside molecular cloud cores, and point to a cloud fragmentation origin for the IMF. Much progress in this field will come from future large submillimeter instruments such as Herschel and ALMA. This revised version was published online in September 2006 with corrections to the Cover Date.  相似文献   
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Many poromechanical studies of rocks give little regard to the micropetrographic observation of their constituents. The aim of this study is to show how such a detailed study can help understand and provide more precision on the poromechanical behaviour of the material. The rock studied here is an oolitic limestone. Micropetrography reveals the nature of the constituents (calcite, mostly in the form of fine‐grained micrite), their abundance, their organization (micrite organized in ooids linked by a calcitic cement, small‐sized highly connected isotropic porosity, scarce unconnected porosity) and the structure of the rock (global isotropy, small heterogeneities due to sedimentological phenomena, no microcracks). Micropetrography completes the information obtained by poromechanics in that it allows the observation of elements deduced from macroscopical tests. The aim of this paper is to show the effect of microporosity on permeability and flow in a rock where microporous grains are in contact with each other.  相似文献   
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